河口船闸金属结构重防腐涂层体系的适应性研究*
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国家自然科学基金项目(52279124,52209156); 江苏交通运输厅科技项目(LSXGH-KT-ZMTC); 重庆交通大学大学生创新创业训练计划项目(s202510618010)


Adaptability of heavy anti-corrosion coating system for metal structure of estuarine ship lock
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    摘要:

    河口船闸频繁暴露在干湿交替与盐水入侵耦合作用下的特殊腐蚀环境,会加速金属结构防腐涂层的劣化,严重威胁其使用寿命和运营安全。针对这一问题,设计一套高频干湿循环自动化试验机,以模拟河口船闸实际服役环境,遴选5种典型重防腐涂层体系进行室内加速腐蚀试验,采用失光率分析、附着力测试、电化学阻抗谱分析等手段,对涂层体系的失光特性、界面结合强度、低频阻抗模值及开路电位等关键参数进行涂层防腐效能分析。重点探讨涂层材料及涂层厚度对其防腐性能的影响,揭示了传统重防腐体系在干湿交替与盐水入侵耦合环境中的劣化规律。结果表明:聚氨酯面漆附着力和保光性优于氯化橡胶,且随着涂层厚度增加(如720 μm体系)能显著提升各电化学指标表现。涂层劣化呈现初期急剧、后期趋缓的特征,综合性能退化与膜厚及材料特性密切相关,综合分析环氧富锌底漆、环氧云铁中间漆、聚氨酯面漆(720 μm体系)整体表现更好。

    Abstract:

    The frequent exposure of the estuarine ship lock to the special corrosive environment of alternating dry and wet conditions and saltwater intrusion can accelerate the deterioration of the anti-corrosion coating on the metal structure,seriously threatening its service life and operational safety.To address this issue,a high-frequency dry-wet cycle automated testing machine is designed to simulate the actual service environment of the estuary ship lock.Five typical heavy-duty anti-corrosion coating systems are selected for indoor accelerated corrosion tests.The key parameters of the coating systems,such as gloss loss,adhesion,low-frequency impedance modulus,and open-circuit potential,are analyzed for coating anti-corrosion effectiveness using methods such as gloss loss analysis, adhesion testing,and electrochemical impedance spectroscopy analysis.The influence of coating materials and coating thickness on the anti-corrosion performance is emphasized,and the deterioration laws of traditional heavy-duty anti-corrosion systems in the alternating dry and wet conditions and saltwater intrusion coupling environment are revealed.The results show that the adhesion and gloss retention of polyurethane topcoat are superior to those of chlorinated rubber,and the electrochemical indicators can be significantly improved with the increase of coating thickness (such as the 720 μm system).The coating deterioration shows a characteristic of rapid initial deterioration followed by a gradual slowdown.The overall performance degradation is closely related to the film thickness and material properties.Comprehensive analysis indicates that the epoxy zinc-rich primer,epoxy mica intermediate coat,and polyurethane topcoat (720 μm system) perform better overall.

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李春泽,吴林键,陆茵茵,等.河口船闸金属结构重防腐涂层体系的适应性研究*[J].水运工程,2026(2):127-136.

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  • 在线发布日期: 2026-03-05
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