海洋环境下混凝土开裂前后钢筋锈蚀产物的微观和力学性能对比分析*
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国家重点研发计划项目(2022YFB2603000)


Comparative analysis on microstructure and mechanical properties of reinforcement corrosion products before and after concrete cracking in marine environment
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    摘要:

    明确钢筋锈蚀产物的微观和力学性能对理解混凝土结构的耐久性失效、建立钢筋混凝土结构的锈胀开裂模型具有重要意义。依托湛江某废弃桥梁和温州某老旧码头,开展真实海洋环境下钢筋锈蚀产物的取样和分析工作。利用X射线衍射仪(XRD)、热重分析仪(TG)、扫描电镜(SEM)等微观表征手段,对钢筋锈蚀产物的化学成分、微观形貌以及体积膨胀率等微观性能进行分析;此外,通过纳米压痕试验测定钢筋锈蚀产物的弹性模量、硬度等力学特征参数。结果表明:混凝土开裂前后,钢筋锈蚀产物的主要成分均为铁的氧化物和羟基氧化物;开裂后浪溅区、开裂前浪溅区、开裂前水位变动区、开裂前水下区钢筋锈蚀产物的体积膨胀系数逐渐降低,分别为2.552 2、2.341 4、2.340 5、1.990 3;混凝土开裂前钢筋锈蚀产物的弹性模量平均值的范围在137.06~154.70 GPa,硬度平均值的范围在1.001 0~1.149 0 GPa;混凝土开裂后钢筋锈蚀产物的弹性模量平均值为125.89 GPa,硬度平均值为0.892 4 GPa。

    Abstract:

    Determining the microstructure and mechanical properties of reinforcement corrosion products is crucial for understanding the concrete structure durability failure and developing the concrete corrosion-induced cracking model.The reinforcement corrosion products before and after concrete cracking are sampled and analyzed on the basis of a decommissioned bridge in Zhanjiang and an aging wharf in Wenzhou,both exposed to the real marine environment.The chemical composition,microstructure,and volume expansion coefficient of corrosion products are measured by X-ray diffraction (XRD),thermogravimetric analysis (TG),and scanning electron microscopy (SEM).The nanoindentation experiments are carried on to determine the elastic modulus and hardness of the corrosion products.The results indicate that the main components of the reinforcement corrosion products before and after concrete cracking are oxides of iron and oxyhydroxides.The volume expansion coefficients of the corrosion products in different zones,including the splash zone after cracking,the splash zone before cracking,the tidal zone before cracking,and the submerged zone before cracking,gradually decrease,with values of 2.552 2,2.341 4,2.340 5,and 1.990 3,respectively.Furthermore,the average elastic modulus of the reinforcement corrosion products before concrete cracking ranges from 137.06 to 154.70 GPa,while the average hardness ranges from 1.001 to 1.149 GPa.After concrete cracking,the average elastic modulus of corrosion product is 125.89 GPa,and the average hardness of corrosion product is 0.892 4 GPa.

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唐博文,汪 伟,朱海威,等.海洋环境下混凝土开裂前后钢筋锈蚀产物的微观和力学性能对比分析*[J].水运工程,2025(7):43-50.

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  • 在线发布日期: 2025-07-15
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